Sikkerhedsdatablad for Indium Phosphide Wafer
Sikkerhedsdatablad for Indium Phosphide Wafer
| Produktnavn: | Indiumfosfid | Udstedelsesdato: |
| SDS nr.: | PAM-001 | 2017/10/15 |
1. PRODUKT- OG VIRKSOMHEDSIDENTIFIKATION
Produktnavn: Indium Phosphide
Kemisk formel: InP Mol. Wt. 145,79
Producent: Powerway Wafer Co.,Limited
Adresse:#506B, Henghui Business Center, No.77, Lingxia Nan Road
High Technology Zone, Huli, Xiamen, 361000
2. FAREIDENTIFIKATION
Giftig ved indånding og ved indtagelse. Giver anledning til farlige nedbrydningsprodukter.
3.KOMPOSITION
Kemikalie: Indiumphosphide
CAS-nr.: 22398-80-7
Ren forbindelse: Ind: 78,8 vægt%
P: 21,2 vægt%
4.FØRSTEHJÆLPSFORANSTALTNINGER
Indånding: Fjern patienten fra eksponering. Søg lægehjælp. Hudkontakt: Vask straks med vand. Hvis der opstår symptomer, søg lægehjælp. Øjenkontakt: Skyl med rent vand eller øjenskylleopløsning i mindst 10 minutter. Indtagelse: Skyl munden med vand. Få øjeblikkelig lægehjælp.
5.BRANDBEKÆMPELSE
Slukningsmidler: Brug tørre ildslukkere, der er egnede til metalbrande.
Særlige farer: Produktet nedbrydes termisk over 300℉ og udvikler giftige dampe af fosfor og oxider af fosfor. Elementært fosfor er brandfarligt. Reaktion med syre og/eller damp kan frigive phosphingas, som er giftig og pyrofor.
Beskyttelsesudstyr: Bær fuldt beskyttelsesudstyr og selvstændigt bre-apparat. Træf passende foranstaltninger for fosfor
6. FORHOLDSREGLER VED UDSLIP VED UHELD
Personlige forholdsregler: Bær beskyttelsesudstyr inklusive handsker og passende åndedrætsværn.
Miljø: Undgå udledning til afløb eller vandløb eller udledning af støv eller dampe til luft.
Spild: Saml alt materiale og overfør det til en lukket beholder til bortskaffelse.
7.HÅNDTERING OG OPBEVARING
Håndtering: Indånd ikke støv. Spis, drik eller ryg ikke under brug. Undgå kontakt med hud og øjne. Atmosfæriske koncentrationer bør kontrolleres i overensstemmelse med standarderne for erhvervsmæssig eksponering. Brug udsugning og ventilation til skæring, slibning, polering eller ætsning. Lad ikke tøj blive forurenet, og brug god hygiejnepraksis.
Opbevaring: Hold beholderen lukket på et køligt, tørt, godt ventileret sted.
8.EKSPONERINGSKONTROL/ PERSONLIGE VÆRNEMIDLER
Standarder for erhvervsmæssig eksponering:
"Indium og forbindelser" UK EH40: OES 0,1mg/m3 (8h TWA)
OES 0,3mg/m3 (15 min ref.)
"Fosfor, gul" UK EH40: OES 0,1mg/m3 (8h TWA)
OES 0.3mg/m3 (15min ref.)
Engineering Controls: Local exhaust ventilation for all mechanical or chemical processing perations. High efficiency dust filtration on extract exhaust outlets. Extract ducting may contain finely divided dust or particles. Maintenance of processing and extract equipment should be carried out using full personal protectve equipment.
Respiratory Protection: All processes should be carried out under extraction. Where high concentrations of dust or decomposition products are likely, air supplied breathing equipment should be used
Hand Protection: Rubber or plastic gloves. Flame-proof gloves if elemental phosphorus is present.
Eye protection: Face shield or safety glasses.
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance & Odour: Dark grey, odourless solid with vitreous lustre
Melting Point (℃): 1062
Density (kg/m3): 4.79
Vapour Pressure: Decomposes with P vapour pressure of 27 atmospheres at the melting temperature.
Solubility:Insoluble in water.
10.STABILITY AND REACTIVITY
Stability: Decomposes to evolve phosphorus vapour if heated above 300℃.
Conditions to Avoid: Excessive heating.Materials to avoid: Reacts with strong acid reducing agents to produce highly toxic phosphine gas.
Hazardous Decomposition Products: Phosphorus (red and yellow) and oxides of phosphorus.
11.TOXICOLOGICAL INFORMATION
Acute: NIOSH #: NL1800000
Toxicity CODEN: ipr-mus LD50: >5000 mgkg JOCHFV
Main acute hazards from decomposition products, phosphine (TLV 0.3ppm), yellow phosphorus and phosphorus pentoxide.
Exposure Routes: Inhalation of dust, phosphine generated by chemical reaction or phosphorus oxides formed by heating in air.Ingestion of dust or particles
Chronic: Chronic effects of exposure to yellow P include bone necrosis of the jaw.
12.ECOLOGICAL INFORMATION
Mobility: The product is involatile and insoluble and will accumulate in the ground.Persistence: The product is expected to be resistant to biodegradation.Bio-accumulation: Not known.
13.DISPOSAL
Product Disposal: Surplus or waste product should be retained wherever possible for recycling. Solids subject to special disposal to landfill.
Container Disposal: Materials contaminated by contact with the product or its processing by-products should be dealt with as special wastes according to local regulatory requirements. Materials contaminated with elemental P should be stored under water or inert gas to avoid possible spontaneous combustion.
14.TRANSPORT INFORMATION
UN Number: Not restricted.
UN Hazard Class: Acute toxicity below range for classification
15.REGULATORY INFORMATION
Labelling information: Harmful
isk Phrases: R20R22 Harmful by inhalation,Harmful if swallowed
Safety Phrases: S2、S20/21 、S22、S45 、Keep out of the reach of children When using do not eat, drink or smoke Do not breathe dust.
In case of accident or if you feel unwell seek medical advice immediately.(show the label where possible)
Chemical Safety Data SheetGBT16483-2008 UN-Recommendations on the transport of dangerous goods -Model regulations Other relevantinformation
16. OTHER INFORMATION
The information contained herein is based on data believed to be accurate. No warranty is expressed or impliedregarding the accuracy of this data.
Liability is expressly disclaimed for loss or injury arising out of use of this information or the use of any materials described.
The implementation of proper measures for the use of the material is the responsibilityof the user and these should be specifically designed according to circumstance and the relevant legal requirements for Health &Safety.
References:
UK HSE Guidance Note EH40 “Occupational Exposure Limits”
UK HSE CHIP96 Approved SupplyList
UN Publication ISBN 92-1-139055-9
J. Occup. Health. 38(1), 1996, 6-12
Hazardous Chemicals Safety Management Regulations(Order No.591)Convention on the Safe Use of Chemicals at Workplaces(Convention No.170)National List of Hazardous Wastes(2016)Chinese occupational disease prevention and control law(2017)
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